Effect of Immersion Time on Crystallinity and Optical Properties of CdTe Thin Films
Main Article Content
Abstract
This study examined the influence of immersion periods in nanoparticles suspension of cadmium telluride (CdTe) prepared by pulsed laser ablation on the structural and optical properties of deposited thin films with a thickness range of 300 to 420 nm. X-ray diffraction (XRD) showed a polycrystalline structure with enhanced crystallinity and an increase in crystallite size from 19 to 21.6 nm with increasing immersion time from 1 to 4 h. Atomic force microscopy (AFM) showed increases in particle diameter and surface roughness with increasing deposition time. These changes were linked with the development of optical absorbance of the deposited films; in addition, the energy gap narrowed from 2.82 to 2.62 eV. Fourier transform infrared spectroscopy (FTIR) confirms the formation of the CdTe structure. These variations make the thin films more suitable for various applications.
Article Details

This work is licensed under a Creative Commons Attribution 4.0 International License.
Tikrit Journal of Pure Science is licensed under the Creative Commons Attribution 4.0 International License, which allows users to copy, create extracts, abstracts, and new works from the article, alter and revise the article, and make commercial use of the article (including reuse and/or resale of the article by commercial entities), provided the user gives appropriate credit (with a link to the formal publication through the relevant DOI), provides a link to the license, indicates if changes were made, and the licensor is not represented as endorsing the use made of the work. The authors hold the copyright for their published work on the Tikrit J. Pure Sci. website, while Tikrit J. Pure Sci. is responsible for appreciate citation of their work, which is released under CC-BY-4.0, enabling the unrestricted use, distribution, and reproduction of an article in any medium, provided that the original work is properly cited.
References
1. Kumar H, Singh M. Consequences of Post-Annealing on Optical, Structural and Electrical Properties of Cadmium Telluride Thin Films for Solar Cells Applications. Int J Thin Fil Sci Tec. 2025;14(1):21-6. https://doi.org/10.18576/ijtfst/140104
2. Jamwal D, Mehta SK. Metal Telluride Nanomaterials: Facile Synthesis, Properties and Applications for Third Generation Devices. ChemistrySelect. 2019;4(6):1943-63.
https://doi.org/10.1002/slct.201803680.
3. Mouhammed AA, Saleh AN. Simulation Effect of Ga2O3 layer thickness on CdTe solar cell by SCAPS-1D. Tikrit Journal of Pure Science. 2019;24(6):110-6. https://doi.org/10.25130/j.v24i6.895
4. Salih, A. I. (2019). Optical dispersion characterization of CZTS thin films prepared by sol-gel at different annealing temperatures. Tikrit Journal of Pure Science, 24(7), 82-88.
5. de Melo O. Introduction to II-VI semiconductors. Handbook of II-VI Semiconductor-Based Sensors and Radiation Detectors: Volume 1, Materials and Technology: Springer; 2023. p. 3-19.
https://doi.org/10.1007/978-3-031-19531-0_1.
6. Salih, A. R. (2024). Optimal Winter and Summer Settings of Solar Photovoltaic Panels for Many Locations in the World. Tikrit Journal of Pure Science, 29, 6.
7. Nayef UM, Muayad MW, Noori AS, Hadi AJ. Synthesis of zinc oxide nanoparticles via laser ablation on porous silicon for gas sensor applications. Journal of Optics. 2025:1-15.
https://doi.org/10.1007/s12596-025-02531-y
8. Kadim AM. Applications of cadmium telluride (CdTe) in nanotechnology. Nanomaterials-Toxicity, Human Health and Environment: IntechOpen; 2019. https://doi.org/10.5772/intechopen.85506
9. Sultan RB, Al Suny A, Hossain MH, Noor T, Chowdhury MH. Particle swarm optimization for performance enhancement of cadmium telluride thin film solar cells by embedded nano-grating structures with a plasmonic metal coating layer. Heliyon. 2024;10(19).
https://doi.org/10.1016/j.heliyon.2024.e38775.
10. Mostafa AM. The Influence of Various Parameters on the Ablation and Deposition Mechanisms in Pulsed Laser Deposition. Plasmonics. 2025:1-19.
https://doi.org/10.1007/s11468-024-02706-6
11. Veleschuk V, Vlasenko O, Vlasenko Z, Gnatyuk V, Levytskyi S. Dependence of the CdTe melting threshold on the pulse duration and wavelength of laser radiation and the parameters of non-equilibrium charge carriers. Ukrainian journal of physics. 2017(62,№ 2):159-65.
https://doi.org/10.15407/ujpe62.02.0159.
12. Singh R, Soni R. Laser-induced heating synthesis of hybrid nanoparticles. Noble Metal-Metal Oxide Hybrid Nanoparticles: Elsevier; 2019. p. 195-238. https://doi.org/10.1016/B978-0-12-814134-2.00011-5.
13. Nyabadza A, McCarthy É, Makhesana M, Heidarinassab S, Plouze A, Vazquez M, et al. A review of physical, chemical and biological synthesis methods of bimetallic nanoparticles and applications in sensing, water treatment, biomedicine, catalysis and hydrogen storage. Advances in colloid and interface science. 2023;321:103010. https://doi.org/10.1016/j.cis.2023.103010.
14. Harif MN, Rahman KS, Rosly HN, Chelvanathan P, Doroody C, Misran H, et al. An approach to alternative post-deposition treatment in CdTe thin films for solar cell applications. Superlattices and Microstructures. 2020; 147: 106687. https://doi.org/10.1016/j.spmi.2020.106687.
15. Chander S, Purohit A, Lal C, Dhaka M. Enhancement of optical and structural properties of vacuum evaporated CdTe thin films. Materials Chemistry and Physics. 2017;185:202-9.
https://doi.org/10.1016/j.matchemphys.2016.10.024.
16. Khrypunov G, Romeo A, Kurdesau F, Bätzner D, Zogg H, Tiwari AN. Recent developments in evaporated CdTe solar cells. Solar energy materials and solar cells. 2006;90(6):664-77.
https://doi.org/10.1016/j.solmat.2005.04.003.
17. Pathok HS, Adhyapak S, Boruah M, Das AK, Saikia PK. The Influence of Deposition Time on the Structural, Morphological, and Optical Properties of Cdmns Thin Films. Morphological and Optical Properties of CdMn Thin Films.
https://doi.org/10.2139/ssrn.4976607.
18. Najm A, Naeem HS, Majdi HS, Hasbullah SA, Hasan HA, Sopian K, et al. An in-depth analysis of the nucleation and growth mechanism of CdS thin film synthesized by the chemical bath deposition (CBD) technique. Scientific Reports. 2022;12(1):15295. https://doi.org/10.1038/s41598-022-19340-z.
19. Saxena N, Kumar P, Gupta V, Kanjilal D. Radiation stability of CBD-grown nanocrystalline CdS films against ion beam irradiation for solar cell applications. Journal of Materials Science: Materials in Electronics. 2018;29:11013-9.
https://doi.org/10.1007/s10854-018-9183-0.
20. Daud MNM, Zakaria A, Jafari A, Ghazali MSM, Abdullah WRW, Zainal Z. Characterization of CdTe films deposited at various bath temperatures and concentrations using electrophoretic deposition. International journal of molecular sciences. 2012;13(5):5706-14.
https://doi.org/10.3390/ijms13055706.
21. Manivannan V, Enzenroth RA, Barth KL, Kohli S, McCurdy PR, Sampath WS. Microstructural features of cadmium telluride photovoltaic thin film devices. Thin Solid Films. 2008;516(6):1209-13. https://doi.org/10.1016/j.tsf.2007.05.043.
22. Arce-Plaza A, Sánchez-Rodríguez F, Courel-Piedrahita M, Galán OV, Hernández-Calderón V, Ramírez-Velasco S, et al. CdTe thin films: deposition techniques and applications. Coatings and Thin-Film Technologies. 2018:131-48. https://doi.org/10.5772/intechopen.79578.
23. Wegner K, Piseri P, Tafreshi HV, Milani P. Cluster beam deposition: a tool for nanoscale science and technology. Journal of Physics D: Applied Physics. 2006;39(22):R439.
https://doi.org/10.1088/0022-3727/39/22/R02.
24. Patil PC, Gaikwad AA, Phase V, Kadam R, Shirsath SE, Chamargore JJ. Rare earth Ce and Y cation co-substitution and its effects on the strain, elasticity, and magnetism of Co-Zn ferrite nanomaterials. Ceramics International. 2025. https://doi.org/10.1016/j.ceramint.2025.02.329
25. Salman MO, Kadhim MA, Khalefa AA. CdO: SnO2 composite UV-Assisted room temperature ozone sensor. Iraqi Journal of Science. 2023:1190-202. https://doi.org/10.24996/ijs.2023.64.3.15.
26. Camacho-Espinosa E, Mis-Fernández R, Loeza-Poot M, Bartolo-Pérez P, Peña J. Band gap analysis for nanometric sputtered CdTe and CdS films. Materials Science and Engineering: B. 2024;303:117281. https://doi.org/10.1016/j.mseb.2024.117281.
27. Usharani K, Balu A. Structural, optical, and electrical properties of Zn-doped CdO thin films fabricated by a simplified spray pyrolysis technique. Acta Metallurgica Sinica (English Letters). 2015;28:64-71. https://doi.org/10.1007/s40195-014-0168-6.
28. Yang J-H, Yin W-J, Park J-S, Ma J, Wei S-H. Review of first-principles study of defect properties of CdTe as a solar cell absorber. Semiconductor Science and Technology. 2016;31(8):083002. https://doi.org/10.1088/0268-1242/31/8/083002.
29. Lalitha S, Sathyamoorthy R, Senthilarasu S, Subbarayan A, Natarajan K. Characterization of CdTe thin film—dependence of structural and optical properties on temperature and thickness. Solar energy materials and solar cells. 2004;82(1-2):187-99. https://doi.org/10.1016/j.solmat.2004.01.017.
30. Ranjbarzadeh S, Omid H, Razmara N. Facile One-Pot Solvothermal Synthesis of Nanocrystalline CdTe with Different Shapes. Int J Nanoparticles Nanotech. 2019;5:023.
https://doi.org/10.35840/2631-5084/5523.
31. Junaid M, Batoo KM, Hussain SG, Khan WQ, Hussain S. Photodegradation of CdTe thin film via PVD for water splitting to generate hydrogen energy. Results in Chemistry. 2023;6:101102. https://doi.org/10.1016/j.rechem.2023.101102.
32. da Costa P, Merízio LG, Wolff N, Terraschke H, de Camargo ASS. Real-time monitoring of CdTe quantum dots growth in aqueous solution. Scientific Reports. 2024;14(1):7884.
https://doi.org/10.1038/s41598-024-57810-8.
33. Cheng P, Wei X, Dai Z, Zhang Y, Yang Y, Liu J, et al. Tunable electronic and optical properties of CdO/ZrS2 heterostructure based on first principles. Chemical Physics. 2025:112654.
https://doi.org/10.1016/j.chemphys.2025.112654
34. Hai HTN, Nguyen TT, Nishibori M, Ishihara T, Edalati K. Photoreforming of plastic waste into valuable products and hydrogen using a high-entropy oxynitride with distorted atomic-scale structure. Applied Catalysis B: Environment and Energy. 2025;365:124968.
https://doi.org/10.1016/j.apcatb.2024.124968
35. Hértilli S, Yahyaoui N, Zeiri N, Baser P, Said M, Saadaoui S. Theoretical modeling of nonlinear optical properties in spheroidal CdTe/ZnTe core/shell quantum dot embedded in various dielectric matrices. Results in Physics. 2024;56:107274. https://doi.org/10.1016/j.rinp.2023.107274.