Synthesis and Characterization Some of Metals (ƖƖ) Complexes' with Mixed Ligands of saccharinate and Isatin Schiff Base
Main Article Content
Abstract
This research paper includes synthesis and characterization of some complexes of Zn(II),Hg(II), Cd(II), Cu(II), Co(II), Ni(II) with mix ligands of saccharinate and Schiff base derived from Isatin. All the synthesized complexes have been characterized by elemental analysis, molar conductance, uv-visible, magnetic susceptibility, atomic absorption , infrared and 1H NMR spectroscopy ,Metal to ligand [M:L] ratio was obtained for all complexes in ethanol. The concluded chemical formulas of the complexes were [M(sac)2(L)2] ,where {M=(Zn(II) , Hg(II) ,Cd(II)} tetrahedral geometry and for the complexes [M(sac)2(L)(H2O)2] ,where (M=Co , Ni and Cu), were octahedral geometry, sac=saccharinate, and L=C14H10N2O2
Article Details

This work is licensed under a Creative Commons Attribution 4.0 International License.
Tikrit Journal of Pure Science is licensed under the Creative Commons Attribution 4.0 International License, which allows users to copy, create extracts, abstracts, and new works from the article, alter and revise the article, and make commercial use of the article (including reuse and/or resale of the article by commercial entities), provided the user gives appropriate credit (with a link to the formal publication through the relevant DOI), provides a link to the license, indicates if changes were made, and the licensor is not represented as endorsing the use made of the work. The authors hold the copyright for their published work on the Tikrit J. Pure Sci. website, while Tikrit J. Pure Sci. is responsible for appreciate citation of their work, which is released under CC-BY-4.0, enabling the unrestricted use, distribution, and reproduction of an article in any medium, provided that the original work is properly cited.
References
[1]-G.G Mohamed, M.M. Omar, A.M. Hindy, Turk.
J. Chem., 30(2006) 361-382.
[2]-G. Cerhiaro and A.M.D. Ferreira, J. Braz. Chem.
Soc.,17(8) (2006)1473-1485.
[3]-S. Konstantinovic, B. Radovanovic, Z. Cakic and
V. Vasic, J. Serb. Chem. Soc., 68(8-9), (2003)641-
647.
[4]-V.K. Sharma, S. Srivastava and A. Srivastava,
Polish J. Chem.,80(2006)387-396.
[5]-V.K. Sharma, A. Srivastava and S. Srivastava, J.
Serb. Chem. Soc.,71(8-9) (2006), 917-928.
[6]-P. Selvam, M. Chandramoham, E. De Clercq, M.
Witvrouw and C. Pannecouque, European J. Pharm.
Sci., 14 (2001) 313-316.
[7]-M. Rajopodhye and F.D. Popp, J. Heterocycl.
Chem., 24(1987) 1637.
[8]-S.N. Pandeya, S. Smitha, M. Jyoti, and S.K.
Sridhar, Acta Pharm., 55 (2005) 27-46.
[9]-A.H. Abadi, S.M. Abou-Seri, D.E. Abdel-
Rahman, C. Klein, O. Lozah, L. Meijer, European J.
Med. Chem, 41 (2006) 296-305.
[10]-K.M.A. Malik, S.Z. Haider, M.A. Hossain, and
M.B. Hursthouse, Acta. Crystallogr., C 40 (1984),
1696.
[11]-M.R. Weihrauch, V. Diehl, and H. Bohlen,
Mediz. Klin., 96(2001),670.
[12]-D.M. Taylor, and D.R. Williams, Trace Element
Medicine and Chelation Therapy, Royal Society of
Chemistry, Cambridge, 97, (1995).
[13]-O. Andersen, and Mini-Rev., Med. Chem., 4
(2004),11.
[14]-K. Wang, R. Li, Y. Cheng, and B. Zhu, Coord.
Chem. Rev., 90(1999) 297.
[15]-K. Wang, Y. Cheng, X. Wang, R. Li, in: A.
Sigel, and H. Sigel, Metal Ions in Biological
Systems., Marcel Dekker, New York, 40, (2003)707.
[16]-Y.I. Binev, C.T. Petkov, and L. Pejov,
Spectrochim., Acta., 56A (2000),1949.
[17]-P. Naumov, and G. Jovanovski, Curr. Org.
Chem., 5 (2001),1059 .
[18]-S. N. Pandeya, P .Yogeeswari , D. Sriram, G.
Nath., Indian J. Pharm. Sci., 64(3) (2002), 209.
[19]-S. Z. Haider, K. M. A. Malik, K. J.Ahmed, H.
Hess, H. Riffel, and M. B. Hursthouse, Inorg. Chim.
Acta, 72(1983) 21.
[20]-F. A. Cotton, G. E. Lewis, C. A. Murillo, W.
Schwotzer and G. Valle , Inorg .Chem.,
23(1984)4038.
[21]-F.A. Cotton, L.R. Falvello, C.A. Murillo and G.
Valle, Z. Anorg. Allg.Chem.,67(1986)540.
22-B.Kamenar,G.Jovanovski and D. Grdenic, Cryst
.Struct .Commun .,11 (1982)263.
[23]-Z.S. Seddigi, Afroza Bann, and G.M. Golzer
Hossain. The Arabian J. Sci. and Engin.,32(2007)
181.
[24]-R. M. Silverstein, G. C. Bassler and T. C.
Morril, 4th Ed; , Jhon Wiley and Sons New York ,
(1981) .
[25]- O.V. Quinzani, S. Tarulli, O.E. Piro, E.J. Baran,
E.E. Castellano, Z. Naturforsch., 52b (1997) 183.
[26]-K. Siddappa, S. B. Mane, and D. Manikprabhu,
The Scientific World J. vol., Article ID 817365(2014)
13 pages.
[27]-Woon, T.C., Thompson L.K and Rohichard.,
Inorg. Chem. Acta., 1(1984) 90-94.
[28]-Pop, V., David, L., Simut, C., Fillip, S. and
Drangan, M., General Conference of the Balkan
Physical Union, (2003) 851.
[29]-S. S. Sawant, V. Pawar, S. Janrao, R. S. Yamgar,
and Y. Nivid, Int J. Pharm and Chem, vol. 3,pp
(2013) 636-644.
[30]-R. M. Silverstein, G. C. Bassler and T. Morrill
,4th Ed., John-Wiley and Sons Inc., New York,
London, (1981).
[31]-D. Sutton, ''Electronic Spectra Transition Metal
Compexes'',1st Ed., Mc. Graw-Hill Publishing,
London, (1968).
[32]-J.V. Quagliano, J. Fujita, G. Franz, D. J. Phillips, J.A. Walusley and S.Y. Tyree, J.Am. Chem .Soc., (1961) 3770-3773.
[33]- R., Akkasali , N. Patil and S.D., Angadi, J. Chem., 2(1): (2009) 81-86.
[34]-K.B.Pandeya,T.S.Waraich,R.C.Gaur and R. P. Singh, J. Inorg. Nucl. Chem., 43(12), (1981)3159-3162.
[35]-B.J. Mccormick and B.P. Stormer, Inorg. Chem., 11(4), (1972)729-735.
[36]- B .N. Figgis ″Introduction to Ligand Field″ ,Interscences ,New York, ,(1967) 48-49,258,319.
[37]-J. C. Bailar, H.J. Emeleus, Sir R. Nyholm and A. F. Trotman-Dickenson, ″Comprehensive Inorganic Chemistry″,1st Ed., Pergamon, press, Oxford, ,(1973) 1151.
[38]- N. Singh, K. Singh and C. Kaw, Bull. Chem. Soc. (Jpn.), 62,(1989)3328.
[39]-R. C. Aggarwal, B. Singh and S. Singh, Indian J.Chem.,21A, ,(1983)161.
[40]- A.D., Kullkarni S.A. Patil and P.S., Badami Int. J. Electrochem. Sci., 4,(2009) 717-729.
[41]-Hua-Rui Hao,Wei Zhao,Jie Zhavg ,yan Qing Miao and Zh-Faug Zhang J. chem. soc. pak., vol 37(2015) No 06.
[42]- Zana S. Al-shwany, M.Sc. Thesis, Tikrit Univ. ,(2013) .
[43]-Pradip Kar, Narayan C. Pradhan, Basudam Adhikari, J. Macromol. Sci. Pure A.,47 ,(2010)282.
[44]-O.lcat Bekircan and H.akan Bektas, J. Molecules, 13(2008),2126-2135; DOI:10.3390.