Annealing temperature effect on the Structure, Morphology and Optical properties of Copper Oxide CuO thin Films

Main Article Content

Najat A.Dahham

Abstract

Copper  oxide (CuO) thin films were  deposited on glass substrates  by (sol-gel ) method using a spin -Coating technique  and the speed of the spin coater was fixed at 3000 rpm for 30 sec and the samples were are annealed at temperatures (250,350,450 and 550) ° C for 1 hrs. The structural, Morphology, and optical properties of the film are determined by using X-ray diffraction (XRD), Atomic force microscopy (AFM) and UV-visible spectroscopy respectively. The XRD patterns showed that copper oxide (CuO) thin films prepared has polycrystalline structure and when increase the annealing temperature of the thin film over than 300° C the thin film turns from phase Cu2O to CuO phase and through examination (AFM) showed that the average grain size increases with the annealing temperature either Optical examinations showed decrease in transmission and increase in absorption coefficient with increase annealing temperature. The prepared thin films have direct energy gap and the value of the optical energy gap decreased with increasing annealing temperature from 3.99 eV to 3.94 eV

Article Details

How to Cite
Najat A.Dahham. (2023). Annealing temperature effect on the Structure, Morphology and Optical properties of Copper Oxide CuO thin Films. Tikrit Journal of Pure Science, 22(6), 115–124. https://doi.org/10.25130/tjps.v22i6.799
Section
Articles

References

[1] I. Bobowska, P. Wojciechowski (2010), "Synthesis of nanostructures of copper compounds and their hybridisation with titanate nanosheets" Journal of Crystal Growth ,no.312,p. 685–691. [2] M. Salavati-Nissari, F. Davar (2009)," Synthesis of copper and copper(I) oxide nanoparticles by thermal decomposition of a new precursor", Mater. Lett, vol,63 ,p.441.

[3]Z.M. JarZebsk (1974),"Oxide Semiconductors", New York.

[4] K.H. Yoon, W.J. Choi, D.H. Kang (2000)."

Photoelectrochemical properties of copper oxide thin films coated on an n-Si substrate". Thin Solid Films, vol.372,p. 250-256.

[5] A.Y. Oral, E. Mensur, M. H. Aslan and E. Basaran (2004), "The preparation of copper(II) oxide thin films and the study of their microstructures and optical properties",Mater. Chem. Phys., vol.83, p.140.

[6]A. Chen, H. Long, X. Li, Y. Li, G. Yang, and P. Lu (2009)," Controlled growth and characteristics of single-phase Cu2O and CuO films by pulsed laser deposition",Vacuum ,vol.83, p.927. [7] G. Papadimitropoulos, N. Vourdas, V. Em. Vamvakas, and D. Davazoglou (2006), "Optical and structural properties of copper oxide thin films grown by oxidation of metal layers",Thin Solid Films ,vol.515,p. 2428-2432 [8] K. H. Yoon, W. J. Choi and D.H. Kang (2000),"

Photoelectrochemical properties of copper oxide thin films coated on an n-Si substrate", Thin Solid Films, vol. 372, p. 250-256. [9] P. Stefanov ,N. Minkovski, I. Balchev, I. Avramova, N. Sabotinov, Ts. Marinova (2006) , "

XPS studies of short pulse laser interaction with copper", Applied Surface Science ,vol.253, p.1046-1050. [10] R. Al-Gaashani, S. Radiman, N. Tabet and A. R. Daud (2011)," Synthesis and optical properties of CuO nanostructures obtained via a novel thermal decomposition method", J. Alloys and Compounds, vol.35 ,p.8761-8769. [11] A.N. Banerjee and K. Chattopadhyay (2005),

"Recent developments in the emerging field of crystalline p-type transparent conducting oxide thin films"Progress in Crystal Growth and Characterization of Material. Vol. 50, p. 52-105.

[12] X.P. Gao, J.L. Bao, G.L. Pan, H.Y. Zhu, P.X. Huang, F. Wu, D.Y. Song (2004)," Preparation and Electrochemical Performance of Polycrystalline and Single Crystalline CuO Nanorods as Anode Materials for Li Ion Battery", J. Phys. Chem, Vol. 108, PP. 5547.1966.

[13] H.M. Xiao, S.Y. Fu, L.P. Zhu, Y.Q. Li, G. Yang, Eur (2007)," Controlled synthesis and characterization of CuO nanostructures through a facile hydrothermal route in the presence of sodium citrate", J. Inorg. Chem, Vol. 14.

[14] H. Fan, L. Yang, W. Hua, X. Wu, Z. Wu, S. Xie, B. Zou (2004)," Controlled synthesis of monodispersed CuO nanocrystals", Nanotechnology, Vol. 15, P. 37.

[15] C.T. Hsieh, J.M. Chen, H.H. Lin, H.C. Shih (2003)," Field emission from various CuO nanostructures", Applied Physics Letters,Vol. 83, P. 3383. [16] S. B. Wanga, C. H. Hsiaoa, S. J. Changa, K. T. Lamb, K. H. Wenb, S. C. Hungc, S. J. Youngd, and B. R. Huange (2011)," A CuO nanowire infrared photodetector", Sensors and Actuators A: Physical, vol. 171,p. 207-211.

[17 ]S. Nandy, A. N. Banerjee, E. Fortunato, and R. Martins (2013), "A Review on Cu2O and CuI -Based p-Type Semiconducting Transparent Oxide Materials: Promising Candidates for New Generation Oxide Based Electronics",Rev. Adv. Sci. Eng., vol.2, p. 273–304 .

[18] P.O. Larsson, A. Andersson, R.L. Wallengerg, B. Svensson (1996)," Catalytic Oxidation of 1,2-Dichlorobenzene over Supported Transition Metal Oxides", J. Catal, vol. 163, p. 279.

[19] W. Chae, J. Ho Yoon, H. Yu, D. Jang, Y. Kim (2004)," Ultraviolet Emission of ZnS Nanoparticles

Confined within a Functionalized Mesoporous Host", J. Phys. Chem., Vol. 108, P. 11509.

[20] M .Ando, T.Kobayashi, M.Haruta (1997)," Size- and support-dependency in the catalysis of gold", Catal. Today, Vol. 36, P. 135.

[ 21] M. R. Johan , M. Sh. Mohd Suan, N. L. Hawari ,H. A. Ching (2011) ," Annealing Effects on the Properties of Copper Oxide Thin Films Prepared by Chemical Deposition" Int. J. Electrochem. Sci., vol.6, p. 6094 - 6104

[22] H. Yang, J. Ouyang , A. Tang , Yu. Xiao , Li. Xianwei , Xi. Dong , Yu .Yongmei (2006),

"Electrochemical synthesis and photocatalytic property of cuprous oxide nanoparticles". Materials Research Bulletin,vol. 41, p.1310–1318,.

[23]A.h. Jareeze (2014)," Optical Properties,Structure,and Morphology of CuO Grown by Thermal Oxidation of Cu thin film on Glass Substrate" , journal of Kufa – physics Vol.6.No.1, p. 36-41

[24]Th. Y. , R. Sami, A. Saleh, F. S. Atallah (2015),"

Study the effect of annealing on the Structure and optical properties of Copper oxide films preperad by Sol-gel Coating ", Tikrit Journal of Pure Science vol. 21 (5) , p.148-153.

[25] S. J.Mohammed, R. Q. A.Al-Ameer (2016),"

Study the Doping Effect of Nickel on some the Structural and Optical Properties of (CuO) Thin", vol: 12, No:1 ,p.60-76.

[26] Aiping Chen, Hua Long, Xiangcheng Li, Yuhua Li, Guang Yang, Peixiang Lu (2009). "Controlled growth and characteristics of single-phase Cu2O and CuO films by pulsed laser deposition" . Vacuum,vol. 83, p.927-930.

[27] Ma, X., Wang, G., Yukimura, K., Sun, M. Surf (2007). Coat. Technol., vol. 201, p.6712.

[28] D. S. Murali, Sh. Kumar, R. J. Choudhary (2015)," Synthesis of Cu2O from CuO thin films: Optical and electrical properties", AIP ADVANCES

, vol.5, p. 047143.

[29] A. Asha Radhakrishnan, B. Baskaran Beena (2014), "Structural and Optical Absorption Analysis of CuO Nanoparticles" , Indian Journal of Advances in Chemical Science , vol.2, p.158-161.

[30] K.Khojier and A.Behju (2012), ''Annealing temperature effect on nanostructure and phase transition of copper oxide thin films’’,Int.J.Nano Dim. 2(3), p. 185-190.

[31]Kasim. U.Isah, Muhammad. B.M, Umar Ahmadu, Uno. E. Uno, Mohammed. I. Kimpa, Jibrin. A.Yabagi (2013), ''Effect of oxidation temperature on the properties of copper oxide thin films prepared from thermally oxidised evaporated copper thin films'', IOSR Journal of Applied Physics (IOSR-JAP) e- ISSN: 2278-4861. Vol. 3, Issue 2 , PP 61-66.

[32] Ch. Kittle (2004) , " Introduction to Solid State Physics", John Wiley &Sons, Inc., 8th Edition,

[33] H. M. Ajeel, Sh. S. B. Jamil, A. A. Jabor and E. H. Nassir (2014), ''The Effect of Annealing on the Structural and Optical Properties of Copper Oxide Thin Films Prepared by SILAR Method''. J. Baghdad for Sci. Vol.11(2),p.718-729.

[34] M. F. Jawad ,R.A.Ismail and K. Z.Yahea,'' Preparation Of nanocrystalline Cu2O thin film by pulsed laser deposition'',Applied Science Department, University of Technology, Baghdad, Iraq. J Mater Sci; Mater Electron vol.22,p.1244-1247.

[35] K. A. Aadim, A. A-K. Hussain, M.R. Abdulameer (2014),'' Effect of annealing temperature and laser pulse energy on the optical properties of CuO films prepared by pulsed laser deposition", Iraqi Journal of Physics, Vol.12, No.23, PP. 97-104.

[36] J. I. Pankove (1971), "Optical Processes in Semiconductors", Prentice-Hall, New Jersey,

[37] G. Busch and H. Schade (1976), "Lectures on solid state physics", Pergaman Press, London.

[38] M. S. Dresselhaus (1998), "Optical Properties of Solids" Part II.

[39]P.Mallick, and S. Sahu (2012), "Structure, Microstructure and optical absorption Analysis of CuO Nanoparticales Synthesised by Sol-Gel Route " ,Nanoscience and Nanotechnology, vol. 2(3),pp.71-74.

[40] S. H. Awad, R. I. Jadaan (2013) ," Study the optical properties of copper oxide thin film deposited by cold spray", AL-Qadisiya Journal For Engineering Sciences Vol. 6 No. 4 ,p.439-454.

[41]S. G. Ovchinnikov, B. A. Gizhevskii, Y. P. Sukhorukov, A.E. Ermakov, M.A. Uimin, E. A. Kozlov, Y. Kotov and A.A.V. Bagazeev (2007)," Specific features of the electronic structure and optical spectra of nanoparticales with strong electron correlations", Phys. Solid State vol. 49,111.