Synthesis and characterization of new metal complexes of thione and phosphines Ligands
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Abstract
The complexes containing mixed of ligands [5-(3-chlorophenyl) -1,3,4-oxadiazole-2-thione(CPoxSH)] and diphosphines Ph2P(CH2)nPPh2 (diphos)(n=1-4), are prepared by the reaction of [Hg(CPoxS)2] or [M(H2O)2(CPoxS)2] (M = Co, Ni ) with one mole proportion of the diphosphine Ph2P(CH2)nPPh2 gave tetrahedral complexes of the type [Hg(CPoxS)2(diphos)]. While gave an octahedral complexes with cobalt(II) and nickel(II) ions of the type [M(H2O)(CPoxS)2(diphos)] when (M = Co and Ni ) receptivity.
The prepared complexes were characterized by molar conductivity, elemental analysis, IR, 1H, 13C-{1H} and 31P-{1H} n.m.r.
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References
1. Raper, E. S., 1985, Coord. Chem. Rev., 61, 115.
2. Raper, E. S., 1994, Coord. Chem. Rev., 129(1-2),
91.
3. Raper, E. S., 1996, Coord. Chem. Rev., 153, 199.
4. Bell, N. A., Clegg, W., Creighton, R. J., Raper, E.
S., 2000, Inorganica Chimica Acta. 303(1),12.
5. Al-Obaidi, K. H.. Ali, B. F Abu-El-Halawa R.,
Abo-Amer A., 2004, Trans. Metal Chem. 29(7), 804.
6. Ma, C., Jiang, Q., Zhang, R, 2004, Polyhedron,
23(5), 779.
7. Gilheany, D.C., Mitchell, C.M., 1990. In The
chemistry of organophosphorus compounds, F.R.
Hartley, Ed.; J. Wiley and Sons: New York, Vol. 1.
8. Cornils, B., Herrmann, A.W., 1998. Aqueousphase
organometallic catalysis, Wiley-VCH :
Weinheim (Chapter 3.2).
9. McFarlane, W., Akrivos, P.D., Aslandis, P.,
Karagiannidis, P., Hatzisymeon, C. Numan, M. and
Kokkou, S. 1998. Inorg. Chim. Acta. 281, 121.
10. Al-Jibori,S. A., Abdullah, A.I., Al-Allaf, T. A. K.,
2007. Trans. Met. Chem. 32,398.
11. Al-Janabi, A.S.M., Abdullah, B.H., Al-Jibori,
S.A., 2009. Orient. J. Chem. V25(2),277.
12. Hadjikakou, S.K., Kubicki, M., 2000. Polyhodron,
19, 2231.
13. a. Sahni, S.K., Gupta, S.P., Sangal SK, Rana
V.B, 1977. J. Inorg. Chem. 39:1048
b. Al-Janabi, A.S.M., Al-soumadaiy , G. A. Khear-
Allah, B. A., 2011. Orient. J. Chem. V27(4),1465.
14. Geary, W. J., 1971. Coord. Chem. Rev. 7, 81.
15. Dey, K., Mukhopadhyaya, S., Sarkar, S., 2004.
Indian J. Chem. 43A,1853
16. Singh, B., Rukhayar, M.M.P., Sinha, R.J., 1977 J.
Inorg. Nucl. Chem. 39,29.
17. Pringle, P. G., 1983.D. Phil Thesis, Leeds
University, U. K.
18. Bellamy L.J., 1975. The Infra-red Spectra of
Complex Molecules, 1st ed Champan & Hall, London.
19. Nakagawa, I., Shimanochi, T., 1964. Spectrochim
Acta. 20,429.
